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Site-Selective Catalysis

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Attention for Chapter 655: Site-Selective Conjugate Addition Through Catalytic Generation of Ion-Pairing Intermediates
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Chapter title
Site-Selective Conjugate Addition Through Catalytic Generation of Ion-Pairing Intermediates
Chapter number 655
Book title
Site-Selective Catalysis
Published in
Topics in current chemistry, August 2015
DOI 10.1007/128_2015_655
Pubmed ID
Book ISBNs
978-3-31-926331-1, 978-3-31-926333-5
Authors

Daisuke Uraguchi, Takashi Ooi

Editors

Takeo Kawabata

Abstract

Site-selectivity in conjugate addition reactions is tightly associated with the principle of vinylogy. Various vinylogous nucleophiles and electrophiles have been applied to stereoselective conjugate additions directed by chiral small-molecule catalysts. This chapter focuses on the systems that control site- and stereoselectivity via chiral ion-pairing intermediates under organocatalytic conditions and describes individual vinylogous substrates in a separate section. Although site-selectivity originates largely from the intrinsic stereoelectronic nature of individual substrates, catalyst-controlled site-selectivity can be attained in certain cases.

Mendeley readers

Mendeley readers

The data shown below were compiled from readership statistics for 8 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
Unknown 8 100%

Demographic breakdown

Readers by professional status Count As %
Student > Ph. D. Student 2 25%
Other 1 13%
Professor 1 13%
Lecturer 1 13%
Researcher 1 13%
Other 1 13%
Unknown 1 13%
Readers by discipline Count As %
Chemistry 6 75%
Design 1 13%
Unknown 1 13%