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Mendeley readers
| Chapter title |
Asymmetric Iridium-Catalyzed C–C Coupling of Chiral Diols via Site-Selective Redox-Triggered Carbonyl Addition
|
|---|---|
| Chapter number | 651 |
| Book title |
Site-Selective Catalysis
|
| Published in |
Topics in current chemistry, July 2015
|
| DOI | 10.1007/128_2015_651 |
| Pubmed ID | |
| Book ISBNs |
978-3-31-926331-1, 978-3-31-926333-5
|
| Authors |
Inji Shin, Michael J. Krische |
| Editors |
Takeo Kawabata |
| Abstract |
Cyclometalated π-allyliridium C,O-benzoate complexes modified by axially chiral chelating phosphine ligands display a pronounced kinetic preference for primary alcohol dehydrogenation, enabling highly site-selective redox-triggered carbonyl additions of chiral primary-secondary 1,3-diols with exceptional levels of catalyst-directed diastereoselectivity. Unlike conventional methods for carbonyl allylation, the present redox-triggered alcohol C-H functionalizations bypass the use of protecting groups, premetalated reagents, and discrete alcohol-to-aldehyde redox reactions. |
Mendeley readers
The data shown below were compiled from readership statistics for 6 Mendeley readers of this research output. Click here to see the associated Mendeley record.
Geographical breakdown
| Country | Count | As % |
|---|---|---|
| Unknown | 6 | 100% |
Demographic breakdown
| Readers by professional status | Count | As % |
|---|---|---|
| Student > Bachelor | 2 | 33% |
| Professor | 1 | 17% |
| Unknown | 3 | 50% |
| Readers by discipline | Count | As % |
|---|---|---|
| Biochemistry, Genetics and Molecular Biology | 2 | 33% |
| Chemistry | 1 | 17% |
| Unknown | 3 | 50% |