The Rare Earths in Modern Science and Technology

Table of Contents

1. Altmetric Badge
   Book Overview
2. Altmetric Badge
   Chapter 1 Rare Earth Reminiscences
3. Altmetric Badge
   Chapter 2 Magnetic Resonance Studies of Metal Cation Transport Across Biological Membranes: Use Of Paramagnetic Lanthanide Ions
4. Altmetric Badge
   Chapter 3 Inter-Lanthanide Ion Energy Transfer Distance Measurements in Biological Systems
5. Altmetric Badge
   Chapter 4 Gadolinium as an EPR and NMR Probe of Ca 2+ Sites in Biological Systems
6. Altmetric Badge
   Chapter 5 Optical Activity of Mixed-Ligand Complexes of Tb(III) with Pyridine-2,6-Dicarboxylic Acid and Hydroxycarboxylic Acids
7. Altmetric Badge
   Chapter 6 Terbium Luminescence as a Probe of Lanthanide Coordination in Solution
8. Altmetric Badge
   Chapter 7 A 160 Tb(III) Probe of the Calcium Binding Sites of Muscle Calcium Binding Parvalbumin
9. Altmetric Badge
   Chapter 8 The Lanthanides as Structural Probes in Peptides
10. Altmetric Badge
    Chapter 9 Multinuclear NMR Study of Three Aqueous Lanthanide Shift Reagents: Complexes with EDTA and Two Macrocyclic Ligands
11. Altmetric Badge
    Chapter 10 Structures of Dithiophosphinate Complexes of the Lanthanides in the Solid and Solution by X-Ray Diffraction and Paramagnetic NMR
12. Altmetric Badge
    Chapter 11 Recent Advances in the Low Valent Approach to f-Element Organo-Metallic Chemistry
13. Altmetric Badge
    Chapter 12 Laser Photochemistry of a Uranium Compound Tailored for 10µ Absorption: U(OCH 3 ) 6
14. Altmetric Badge
    Chapter 13 New Stoichiometric and Catalytic Pentamethylcyclopentadienyl Organoactinide Chemistry
15. Altmetric Badge
    Chapter 14 Choosing a Coordination Number for Ln(III): 1:1, 1:2, 2:1, 3:2 and 4:3 Complexes with Crown Ethers
16. Altmetric Badge
    Chapter 15 A Systematic Study of the Complexation of Di- and Tri-Valent Lanthanide Ions by Macrocycles of Varying Size
17. Altmetric Badge
    Chapter 16 Octahedral Compounds of Lanthanides: Trimethylphosphine Oxide (tmpo) as Ligand
18. Altmetric Badge
    Chapter 17 Amine Complexes of Divalent Europium
19. Altmetric Badge
    Chapter 18 High Coordination Polyhedra of Trivalent Rare Earth Ions
20. Altmetric Badge
    Chapter 19 Erbium Chloride Complexation in Aqueous DMF
21. Altmetric Badge
    Chapter 20 Lanthanide Hexafluoroantimonate Complexes of Hexamethylphosphoramide
22. Altmetric Badge
    Chapter 21 Parametrisation of the MCD-Spectra of Rare Earths: Example of Pr 3>+ in PVA-Matrix
23. Altmetric Badge
    Chapter 22 Ab-Initio Calculation of Lanthanide Crystal Field Parameters and Transition Probabilities
24. Altmetric Badge
    Chapter 23 On the Origin of Resonance Lines in 3d Emission Spectra of Rare Earths
25. Altmetric Badge
    Chapter 24 Transition Intensities for Nd 3+ in Crystals
26. Altmetric Badge
    Chapter 25 Truncation Effects on Crystal Field Calculations for The 4f 6 (Eu 3+ ) Configuration in Solids
27. Altmetric Badge
    Chapter 26 Study of M 4,5 -Level Soft X-Ray Appearance Potential Spectra of Selected Rare Earths
28. Altmetric Badge
    Chapter 27 The Effect of Multiplet Splitting of the 4d Levels in Rare Earth Elements on Their X-Ray Spectra
29. Altmetric Badge
    Chapter 28 Optical Spectra, Energy Levels, and Crystal-Field Analysis of Tripositive Rare Earth Ions in Y 2 O 3 : I. Kramers Ions in C 2 Sites
30. Altmetric Badge
    Chapter 29 Sm 2+ Activated Mixed Fluorides: Synthesis and Fluorescence
31. Altmetric Badge
    Chapter 30 Electric and Magnetic Dipole Strengths of f-f Transitions in Cubic Cs 2 NaYCl 6 :Ln 3+ Systems
32. Altmetric Badge
    Chapter 31 Absorption Spectrophotometric Characterization of Sm(II), Sm(III), and Sm(II/III) Bromides and Sm(III) Oxybromide in the Solid State
33. Altmetric Badge
    Chapter 32 Cascade Laser Action in Tm 3+ :YLF
34. Altmetric Badge
    Chapter 33 Laser Induced Luminescence of Pr 3+ in CaF 2 Attributed to Different Local Site Symmetries
35. Altmetric Badge
    Chapter 34 Photoconductivity Due to Autoionization of Divalent Rare Earth Impurities in Crystals Having the Fluorite Structure
36. Altmetric Badge
    Chapter 35 The Effect of Structural Environment on the Absorption Spectra of Selected Lanthanide Sesquioxides
37. Altmetric Badge
    Chapter 36 The Ce 3+ →Tb 3+ Transfer in Phosphate Host Lattices
38. Altmetric Badge
    Chapter 37 Laser Excited Luminescence of Tb 3+ , Eu 3+ -Activated Ferroelectric Gadolinium Molybdate (GMO)
39. Altmetric Badge
    Chapter 38 Luminescence of High-Pressure Phases of Eu 2+ Activated Alkaline Earth Borates and Silicates
40. Altmetric Badge
    Chapter 39 PMR Spectroscopic Studies of Lanthanide Aminocarboxylate Complexes
41. Altmetric Badge
    Chapter 40 The Interaction of 1:1 and 1:2 Lanthanide-Edta Chelates with Alkali Cations: Aqueous Relaxation Reagents for Metal Nuclide NMR
42. Altmetric Badge
    Chapter 41 Luminescence of L-(-)-Tryptophan in DMSO at 77 K in the Presence of Tb 3+
43. Altmetric Badge
    Chapter 42 Hypersensitivity in the 4 f −4 f Absorption Spectra of Er 3+ and Ho 3+ Complexes
44. Altmetric Badge
    Chapter 43 Possible Symmetries of the Coordination Sphere of Eu 3+ in DMSO via a Correlation of Magnetic Circular Dichroism (MCD) with Absorption and Emission Spectra
45. Altmetric Badge
    Chapter 44 Diphenyl-Phosphinyl-Morpholide (DPPM) Lanthanide Salt Adducts: Nd 3+ and Eu 3+ Spectra
46. Altmetric Badge
    Chapter 45 Adducts of Lanthanide Trifluoromethanesulfonates and Tetramethylene Sulfoxide (TMSO)
47. Altmetric Badge
    Chapter 46 Photoreduction of Ytterbium and Samarium
48. Altmetric Badge
    Chapter 47 CeN: Phase Relationships and Enthalpies of Solution
49. Altmetric Badge
    Chapter 48 Enthalpies of Solution and Lattice Constant Anomalies of Sm 3 S 4 - Sm 2 S 3 Solid Solutions
50. Altmetric Badge
    Chapter 49 High Temperature Phase Diagram and Enthalpies of Solution of TmSe
51. Altmetric Badge
    Chapter 50 Densities and Concentration of Defects in TmSe
52. Altmetric Badge
    Chapter 51 Preparation and Thermoelectric Properties of Some Rare Earth Chalcogenides
53. Altmetric Badge
    Chapter 52 Thermal Decomposition of Rare Earth Sulfate and Selenate Hydrates
54. Altmetric Badge
    Chapter 53 Rare Earth Oxysulfide/Oxysulfate Equilibria At 1100–1500K
55. Altmetric Badge
    Chapter 54 Phase Studies and Selective Oxidation in Rare Earth-Molybdenum-Oxide Systems, Ln 2 O 3 -MoO 2 -MoO 3
56. Altmetric Badge
    Chapter 55 Correlation of Spectral and Heat-Capacity Schottky Contributions for Dy 2 O 3 , Er 2 O 3 , and Yb 2 O 3
57. Altmetric Badge
    Chapter 56 Enthalpy of Formation of Barium Lanthanide(IV) Oxides: BaCeO 3 , BaPrO 3 , and BaTbO 3
58. Altmetric Badge
    Chapter 57 On Mixed Crystals of Pr 1−y Tb y O x Grown Under High Oxygen Pressures
59. Altmetric Badge
    Chapter 58 A Kinetic Study of the Oxidation of Zeta Phase Praseodymium Oxide: $$\frac{{10}}{9}{\Pr _9}{O_{16}} + \frac{1}{9}{O_2} \to {\Pr _{10}}{0_{18}}$$
60. Altmetric Badge
    Chapter 59 Predicted Stabilities of Rare Earth Dihalides
61. Altmetric Badge
    Chapter 60 Vaporization and Thermodynamic Properties of Samarium Dicarbide and Nonstoichiometric Disamarium Tricarbide
62. Altmetric Badge
    Chapter 61 Complexity of Phase Equilibria in the MM-Co-Fe System Between 2:7 and 1:5 Stoichiometries
63. Altmetric Badge
    Chapter 62 Low Temperature-High Magnetic Field Heat Capacity Studies of Weakly and Nearly Ferromagnetic and Mixed Valence Rare Earth Materials
64. Altmetric Badge
    Chapter 63 Anomalous Behavior of Cerium and Europium Ions in Ternary Molybdenum Chalcogenides (Chevrel Phases)
65. Altmetric Badge
    Chapter 64 New Fluorides with Ce IV , Pr IV , Nd IV , Tb IV , and Dy IV
66. Altmetric Badge
    Chapter 65 Ternary Halides of the Rare Earth Elements: Phases and Structures
67. Altmetric Badge
    Chapter 66 Investigation of the “Diadochic” Incorporation of the Rare Earth Elements in CaF 2 at Elevated Temperature and Pressure
68. Altmetric Badge
    Chapter 67 Crystal Structures of EumgF 4 , SmMgF 4 and SrMgF 4
69. Altmetric Badge
    Chapter 68 Structural Phase Transitions in Cs 2 NaLnCl 6
70. Altmetric Badge
    Chapter 69 Synthesis and Crystal Data for Alkaline Earth-Lanthanide Phosphates with the Eulytite Structure
71. Altmetric Badge
    Chapter 70 The Crystal Structure and Stoichiometry of the Ca 2+x Nd 8-x (SiO 4 ) 6 O 2-1/2x System
72. Altmetric Badge
    Chapter 71 Electron Beam-Induced Reduction of TbO 2−δ : A High Resolution Electron Microscope Study
73. Altmetric Badge
    Chapter 72 Crystal Structure and Properties of (LaO) CuS and (LaO) AgS
74. Altmetric Badge
    Chapter 73 The Crystal Chemistry of the Europium Arsenides
75. Altmetric Badge
    Chapter 74 Crystal Structures and Phase Relationships within Ternary Systems: Rare Earth Metal-Noble Metal-Boron
76. Altmetric Badge
    Chapter 75 Fast Diffusion and Electrotransport of Cobalt, Iron and Nickel in α-Yttrium
77. Altmetric Badge
    Chapter 76 Ternary Compounds In RE(Au,Ga) 2 and RE(Ag,Ga) 2 Alloys
78. Altmetric Badge
    Chapter 77 Magnetic Properties of ErM 3 , M = (Ni, Fe, Co)
79. Altmetric Badge
    Chapter 78 Transport and Magnetic Properties of the Gd 4 (Co 1−x Ni x ) 3 Series (0≤×≤: 0.2)
80. Altmetric Badge
    Chapter 79 Structures and Magnetism of Some Polycomponent 2:17 Rare Earth- Transition Metal Systems
81. Altmetric Badge
    Chapter 80 Evidence for the Noncollinearity of the Magnetic Structure of Er 6 Mn 23
82. Altmetric Badge
    Chapter 81 Mösbauer Investigation of the Effect of Annealing on the Ordering Temperature of Amorphous DyFe 2
83. Altmetric Badge
    Chapter 82 Magnetization and 55 Mn Hyperfine Field in RMn 2 (R = Rare Earth) Intermetallic Compounds
84. Altmetric Badge
    Chapter 83 Magnetic Properties of Cubic and Hexagonal HoMn 2
85. Altmetric Badge
    Chapter 84 Susceptibility Densities in the Pauli Paramagnets YNi 5 and CeNi 5
86. Altmetric Badge
    Chapter 85 Thermal Variation of Anisotropies of Cobalt in YCo 5 and NdCo 5 up to 450 K
87. Altmetric Badge
    Chapter 86 The Magnetic Structure of Y(Mm 1−x Fe x ) 12
88. Altmetric Badge
    Chapter 87 Magnetic Characteristics of the Intermetallic Compounds R 2 Ni 17−x Al x (R = Gd,Tb)
89. Altmetric Badge
    Chapter 88 Observation of Spiral Spin Antiferromagnetic Domains in Single Crystal Terbium
90. Altmetric Badge
    Chapter 89 Crystal Field and Quadrupolar Effects on the Third-Order Magnetic Susceptibility
91. Altmetric Badge
    Chapter 90 Magnetic Properties of Some Single Crystal Rare Earth Tetraborides
92. Altmetric Badge
    Chapter 91 Transferred Hyperfine Interactions and Quadrupole Effects for the Diamagnetic Ions in Rare-Earth Elpasolites, Cs 2 NaLnCl 6
93. Altmetric Badge
    Chapter 92 Structure-Property Interplay in the System RTiO 3 : R = Lanthanide (III)
94. Altmetric Badge
    Chapter 93 Some Magnetic Properties of the System La x Gd 1−x TiO 3
95. Altmetric Badge
    Chapter 94 Zero Field Temperature Depencence of the Rare Earth Sublattice Magnetization in RTiO 3 ; R = Tb, Dy, Ho, Er and Tm
96. Altmetric Badge
    Chapter 95 Magnetic and Structural Properties of CeSb 1−x Te x Mixed Compounds
97. Altmetric Badge
    Chapter 96 Effects of the Non-Stoichiometry on the Transport Properties of CeSb
98. Altmetric Badge
    Chapter 97 Low-Temperature Behavior of DyS, DySe, HoS and HoSe
99. Altmetric Badge
    Chapter 98 Electrical Resistivity and Magnetic Field Effects of NdS 3−x V x S 4
100. Altmetric Badge
     Chapter 99 Faraday Rotation of Rare Earth Alkali Germanate Glasses
101. Altmetric Badge
     Chapter 100 Using NMR to Study the Properties of Rare-Earth Materials Containing Hydrogen
102. Altmetric Badge
     Chapter 101 Magnetic and Structural Properties of Y 6 Mn 2 3 D 2 3
103. Altmetric Badge
     Chapter 102 Magnetic and Structural Properties of Th 6 Mn 2 3 D x and Y 6 Mn 2 3 D x
104. Altmetric Badge
     Chapter 103 Valence Bonding, Atomic Volumes, and Coordination Numbers for Y 6 Mn 23 , Th 6 Mn 23 , and their Hydrides
105. Altmetric Badge
     Chapter 104 Structure of Al, Cu and Si Substituted LaNi 5 and of the Corresponding β-Deuterides from Powder Neutron Diffraction. Localized Diffusion Mode of Hydrogen in LaNi 5 and Al and Mn Substituted Compounds from Quasielastic Neutron Scattering
106. Altmetric Badge
     Chapter 105 Thermodynamic and Magnetic Properties of LaNi 5−x Fe x Compounds and Their Hydrides
107. Altmetric Badge
     Chapter 106 Thermodynamic Properties of LaNi 4 M Compounds and Their Hydrides
108. Altmetric Badge
     Chapter 107 Hydrogen Desorption Rates in LaNi 5−x Al x -H
109. Altmetric Badge
     Chapter 108 Structure-Reactivity Studies on the Extraction of Lanthanides by Dialkyl Isopropylphosphonates
110. Altmetric Badge
     Chapter 109 Separation of the Rare Earths and Some Polyvalent Cations on Inorganic Ion Exchangers
111. Altmetric Badge
     Chapter 110 Solvent Extraction Behavior of Lanthanides with Di(2-Ethylhexyl) Isopropylphosphonate
112. Altmetric Badge
     Chapter 111 Spectrophotometric Determination of Rare Earths in Ligand Buffer Masking Systems
113. Altmetric Badge
     Chapter 112 Spectrophotometric Determination of Trace Amounts of Copper in High-Purity Rare Earth with α,ß,γ,δ-Tetra-(4-Trimethylammonium-Phenyl) Porphine
114. Altmetric Badge
     Chapter 113 Rare Earth Ion Selective Electrodes: II. Europium and Praseodymium Compound Membranes
115. Altmetric Badge
     Chapter 114 Analysis of Rare Earth Elements in Ore Concentrate Samples using Direct Current Plasma Spectrometry
116. Altmetric Badge
     Chapter 115 Behavior of REE in Geological and Biological Systems
117. Altmetric Badge
     Chapter 116 Trends in Rare Earth Metal Consumption for Steel Applications in the 1980’s
118. Altmetric Badge
     Chapter 117 The Use of Rare Earths in Photovoltaics
119. Altmetric Badge
     Chapter 118 Preparing Rare Earth Silicon Iron Alloys
120. Altmetric Badge
     Chapter 119 Catalysis Using Rare Earth and Actinide Internetallics Containing Fe, Co, Ni and Cu
121. Altmetric Badge
     Chapter 120 Electrochemical Corrosion of Lanthanum Chromite and Yttrium Chromite in Coal Slag